Titrations in non-aqueous solvents (Huber, Walter)

Non aqueous titrations pdf

Polarographic Reduction of Hydrogen Ion in Non-aqueous Solvents

Sommary-_The polarographic reduction of hydrogen ion, furnished by dissociation of a Brransted acid or present in the undissociated Brsnsted acid, is reviewed for the situation where a solvent other than water is involved. INTRODUCTION THE electrochemical reduction of hydrogen ion in aqueous solution has long been a major problem in electrochemistry, as indicated by the voluminous literature on...

Coulometric titration of acids in non-aqueous solvents.

Coulometric titrations of mineral acids, sulphonic acids, carboxylic acids, enols, imides and phenols have been carried out in t-butanol or in acetone with electrically generated tetrabutylammonium hydroxide. Either a potentiometric titration or a visual indicator end-point may be used. The amount of acid titrated ranges from 10 to 60 muequiv, and the precision and accuracy of the method are ex...

Non-aqueous solvents for DNP surface enhanced NMR spectroscopy.

A series of non-aqueous solvents combined with the exogenous biradical bTbK are developed for DNP NMR that yield enhancements comparable to the best available water based systems. 1,1,2,2-tetrachloroethane appears to be one of the most promising organic solvents for DNP solid-state NMR. Here this results in a reduction in experimental times by a factor of 1000. These new solvents are demonstrat...

The role of initiator on the dispersibility of polystyrene microgels in non-aqueous solvents

Non-aqueous microgel particles are commonly synthesised in water, dried, and then redispersed in non-aqueous solvents. An important factor to consider when synthesising such particles is the initiator, which can determine how well the particles disperse in solvents. Polystyrene microgel particles were made with three different initiators. When a neutral, oil soluble initiator (azobisisobutyroni...